The clausius clapeyron equation relates the latent heat heat of transformation of vaporization or condensation to the rate of change of vapour pressure with temperature. The relationship between the temperature of a liquid and its vapor pressure is not a straight line. Elija sus unidades preferidas e ingrese lo siguiente. Chapter 14 the clausius clapeyron equation before starting this chapter, it would probably be a good idea to reread sections 9. The clausiusclapeyron equation relates the latent heat heat of transformation of vaporization or condensation to the rate of change of vapour pressure with temperature.
Scribd is the worlds largest social reading and publishing site. Use boettchers results as a starting point and apply the clausiusclapeyron equation to determine the temperature of reaction at 10 kbar. We can derive the equation for e s using two concepts you may have heard of and will learn about later. Mathematically, where is the slope of the tangent to the coexistence curve at any point, is the specific latent heat, is the temperature, is the specific volume change of the phase. Nov 18, 2019 use boettchers results as a starting point and apply the clausiusclapeyron equation to determine the temperature of reaction at 10 kbar. The clausiusclapeyron relation, named after rudolf clausius and benoit paul emile clapeyron, is a way of characterizing a discontinuous phase transition between two phases of matter of a single constituent.
Jose manuel becerra espinosa 1 ecuaciones y desigualdades unidad vii vii. So we can calculate the slope of the reaction at 1bar and use that to extrapolate. The vapor pressure of water, for example, increases significantly more rapidly than the temperature of the system. Chapter 14 the clausiusclapeyron equation before starting this chapter, it would probably be a good idea to reread sections 9. Answer this is a solidsolid reaction, so it is reasonable to assume that.
The clausiusclapeyron relation gives the slope of the tangents to this curve. Clapeyron equation and clapeyrons equation redirect here. Descargue como pdf, txt o lea en linea desde scribd. The clausiusclapeyron equation can be also applied to sublimation. Descargue como pptx, pdf, txt o lea en linea desde scribd.
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